Пределы определения элементов (6
) разными методами в породах и растворах.
|
Пределы определения элементов (6
)
|
Элемент
|
AAS-Flame [2]
|
AAS-Graphite furnace [3]
|
ICP-AES [1]
|
ICP-MS [1]
|
AES-Arc
|
XRF
|
INAA
|
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock (Cu) [1]
(ppm)
|
Rock (C) [2]
(ppm)
|
Rock [1] (ppm)
|
Rock [3] (ppm)
|
Rock [1] (ppm)
|
1 H
|
|
|
|
|
|
|
|
|
|
|
|
|
|
2 He
|
|
|
|
|
|
|
|
|
|
|
|
|
|
3 Li
|
1 (*)
|
0.003
|
0.01
|
0.00003
|
3
|
0.045
|
8
|
0.008
|
0.08
|
14.4
|
|
|
|
4 Be
|
0.6
|
0.003
|
0.0012
|
0.000006
|
0.1
|
0.00054
|
|
|
2
|
0.8
|
|
|
|
5 B
|
90 (*)
|
2.1
|
|
|
2 (*)
|
0.045
|
4
|
0.004
|
20
|
6.0
|
|
+
|
|
6 C
|
|
|
|
|
70 (*)
|
0.35
|
|
0.1
|
|
|
|
|
|
7 N
|
|
|
|
|
|
|
|
|
|
|
|
+
|
|
8 O
|
|
|
|
|
|
|
|
|
|
|
|
|
|
9 F
|
|
|
|
|
|
|
|
|
|
|
5400
|
|
|
10 Ne
|
|
|
|
|
|
|
|
|
|
|
|
|
|
11 Na
|
0.2
|
0.001
|
0.0018
|
0.000009
|
12 (*)
|
0.058
|
4
|
0.004
|
500
|
|
1190
|
250
|
1000
|
12 Mg
|
0.12
|
0.0006
|
0.00012
|
0.0000006
|
12
|
0.060
|
2
|
0.002
|
|
|
603
|
|
|
13 Al
|
12
|
0.06
|
0.006
|
0.00003
|
9 (*)
|
0.046
|
3
|
0.003
|
|
|
260
|
|
|
14 Si
|
90
|
0.45
|
0.12
|
0.0006
|
5 (*)
|
0.024
|
|
|
|
|
159
|
|
|
15 P
|
24000
|
120
|
12
|
0.06
|
30 (*)
|
0.152
|
600
|
0.6
|
2000
|
|
118
|
|
|
16 S
|
|
|
|
|
|
0.1
|
200
|
0.2
|
|
|
20
|
|
|
17 Cl
|
|
|
|
|
|
|
|
|
|
|
20
|
|
|
18 Ar
|
|
|
|
|
|
|
|
|
|
|
|
|
|
19 K
|
0.6
|
0.003
|
0.0018
|
0.000009
|
2400 (*)
|
12.0
|
|
|
7000
|
|
6.6
|
+
|
|
20 Ca
|
0.6
|
0.003
|
0.006
|
0.00003
|
4 (*)
|
0.020
|
|
|
|
|
8.6
|
+
|
|
21 Sc
|
10 (*)
|
0.15
|
|
|
2
|
0.030
|
6
|
0.006
|
5
|
1
|
8.0
|
0.5
|
0.03
|
22 Ti
|
42
|
0.21
|
0.18
|
0.0009
|
1.5 (*)
|
0.076
|
4
|
0.004
|
|
|
3.6
|
+
|
|
23 V
|
1 (*)
|
0.15
|
0.002
|
0.0003
|
4
|
0.020
|
4
|
0.004
|
3
|
2
|
10
|
+
|
|
24 Cr
|
3 (*)
|
0.009
|
0.005
|
0.000015
|
3
|
0.014
|
2
|
0.002
|
2
|
2
|
10
|
40
|
1.5
|
Продолжение табл 21.
|
Пределы определения элементов (6
)
|
Элемент
|
AAS-Flame
|
AAS-Graphite furnace
|
ICP-AES
|
ICP-MS
|
AES-Arc
|
XRF
|
INAA
|
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock [1]
(ppm)
|
Rock [2]
(ppm)
|
Rock [1] (ppm)
|
Rock [3] (ppm)
|
Rock [1] (ppm)
|
25 Mn
|
1.2
|
0.06
|
0.0004
|
0.000002
|
15
|
0.0028
|
4
|
0.004
|
|
6
|
10
|
+
|
|
26 Fe
|
3
|
0.015
|
0.006
|
0.00003
|
2.5 (*)
|
0.0124
|
4
|
0.004
|
|
2000
|
9.8
|
2500
|
100
|
27 Co
|
2 (*)
|
0.015
|
0.0032
|
0.000024
|
2
|
0.014
|
2
|
0.002
|
2
|
1.6
|
6
|
2.5
|
0.14
|
28 Ni
|
3 (*)
|
0.015
|
0.03
|
0.00015
|
6
|
0.30
|
4
|
0.004
|
14
|
2
|
6
|
4.0
|
|
29 Cu
|
1 (*)
|
0.009
|
0.0023
|
0.000021
|
5
|
0.0108
|
2
|
0.002
|
2
|
0.06
|
6
|
|
|
30 Zn
|
0.8
|
0.003
|
0.0016
|
0.000006
|
5
|
0.0080
|
6
|
0.006
|
24
|
6
|
9
|
100
|
|
31 Ga
|
42
|
0.21
|
0.012
|
0.00006
|
16
|
0.092
|
|
|
4
|
2
|
|
|
|
32 Ge
|
60
|
0.3
|
0.06
|
0.0003
|
40
|
0.096
|
4
|
0.004
|
2
|
0.2
|
|
|
|
33 As
|
60
|
0.3
|
0.06
|
0.0003
|
15
|
0.106
|
60
|
0.060
|
200
|
2
|
10
|
1
|
|
34 Se
|
120
|
0.6
|
0.06
|
0.0003
|
50
|
0.15
|
100
|
0.1
|
|
|
|
4
|
|
35 Br
|
|
|
|
|
|
|
|
|
|
|
|
0.6
|
|
36 Kr
|
|
|
|
|
|
|
|
|
|
|
|
|
|
37 Rb
|
1 (*)
|
0.015
|
|
|
15000(*)
|
75
|
2
|
0.002
|
6
|
|
3
|
15
|
10
|
38 Sr
|
1 (*)
|
0.015
|
0.002
|
0.00003
|
2
|
0.00084
|
2
|
0.002
|
1
|
2
|
3
|
|
|
39 Y
|
50 (*)
|
0.6
|
2.5
|
0.03
|
2
|
0.0070
|
2
|
0.002
|
6
|
2
|
3
|
|
|
40 Zr
|
90 (*)
|
4.5
|
|
|
6
|
0.0142
|
2
|
0.002
|
6
|
2
|
6
|
+
|
100
|
41 Nb
|
90 (*)
|
6.0
|
|
|
10
|
0.072
|
2
|
0.002
|
4
|
1.6
|
6
|
|
|
42 Mo
|
6 (*)
|
0.06
|
0.009
|
0.00009
|
10
|
|
4
|
0.004
|
4
|
1.0
|
6
|
1.5
|
|
43 Tc
|
|
|
|
|
|
|
|
|
|
|
|
|
|
44 Ru
|
180
|
0.9
|
|
|
12 (*)
|
0.060
|
8
|
0.008
|
1
|
|
|
|
|
45 Rh
|
3
|
0.015
|
0.06
|
0.0003
|
18 (*)
|
0.088
|
2
|
0.002
|
2
|
|
|
|
|
46 Pd
|
9
|
0.045
|
0.06
|
0.0003
|
18 (*)
|
0.088
|
1
|
0.001
|
0.5
|
|
|
|
|
47 Ag
|
1 (*)
|
0.006
|
0.001
|
0.000006
|
5
|
0.014
|
2
|
0.002
|
0.2
|
0.06
|
|
3
|
|
48 Cd
|
0.8 (*)
|
0.003
|
0.00016
|
0.0000006
|
5
|
0.0068
|
2
|
0.002
|
30
|
0.6
|
|
|
|
49 In
|
24
|
0.12
|
0.012
|
0.00006
|
25 (*)
|
0.126
|
|
0.002
|
10
|
0.04
|
|
100
|
|
50 Sn
|
20 (*)
|
0.3
|
0.012
|
0.00018
|
6
|
0.09
|
4
|
0.004
|
6
|
0.2
|
|
|
|
Продолжение
таблицы 21.
|
Пределы определения элементов (6
)
|
Элемент
|
AAS-Flame
|
AAS-Graphite furnace
|
ICP-AES
|
ICP-MS
|
AES-Arc
|
XRF
|
INAA
|
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock [1]
(ppm)
|
Rock [2]
(ppm)
|
Rock [1] (ppm)
|
Rock [3] (ppm)
|
Rock [1] (ppm)
|
51 Sb
|
5 (*)
|
0.12
|
0.01
|
0.00024
|
20
|
0.064
|
|
|
135
|
0.4
|
|
0.1
|
|
52 Te
|
30
|
0.15
|
0.03
|
0.00015
|
16 (*)
|
0.352
|
2
|
0.002
|
640
|
0.8
|
|
|
|
53 I
|
|
|
|
|
|
|
|
|
|
|
|
|
|
54 Xe
|
|
|
|
|
|
|
|
|
|
|
|
|
|
55 Cs
|
12
|
0.06
|
0.012
|
0.00006
|
16600(*)
|
83.0
|
2
|
0.002
|
200
|
|
|
0.6
|
0.17
|
56 Ba
|
10 (*)
|
0.06
|
0.02
|
0.00012
|
1
|
0.0026
|
2
|
0.002
|
2
|
140
|
24
|
80
|
60
|
57 La
|
1200
|
6.0
|
0.3
|
0.0015
|
7
|
0.022
|
4
|
0.004
|
30
|
7.2
|
15
|
1.5
|
0.5
|
58 Ce
|
|
|
|
|
15
|
0.104
|
3
|
0.003
|
40
|
20
|
|
+
|
1.5
|
59 Pr
|
3000
|
15.0
|
|
|
40
|
0.094
|
2
|
0.002
|
4
|
|
3
|
|
|
60 Nd
|
600
|
3.0
|
|
|
30
|
0.272
|
4
|
0.004
|
30
|
|
36
|
+
|
1.5
|
61 Pm
|
|
|
|
|
|
|
|
|
|
|
|
|
|
62 Sm
|
600
|
3.0
|
|
|
15
|
0.166
|
4
|
0.004
|
10
|
|
|
0.05
|
0.1
|
63 Eu
|
18
|
0.09
|
0.06
|
0.0003
|
2
|
0.054
|
4
|
0.004
|
2
|
|
|
2
|
0.05
|
64 Gd
|
1200
|
6.0
|
4.8
|
0.024
|
5
|
0.050
|
4
|
0.004
|
6
|
|
|
|
3.9
|
65 Tb
|
600
|
3.0
|
|
|
80
|
0.120
|
4
|
0.004
|
95
|
|
|
|
0.9
|
66 Dy
|
30
|
0.15
|
|
|
15
|
0.054
|
2
|
0.002
|
6
|
|
|
+
|
|
67 Ho
|
36
|
0.18
|
0.42
|
0.0021
|
15
|
0.0114
|
1
|
0.001
|
2
|
|
|
|
1.7
|
68 Er
|
21
|
0.12
|
0.16
|
0.0009
|
15
|
0.036
|
4
|
0.004
|
5
|
|
|
|
|
69 Tm
|
60
|
0.3
|
|
|
2 (*)
|
0.0104
|
1
|
0.001
|
6
|
|
|
+
|
0.34
|
70 Yb
|
24
|
0.12
|
0.006
|
0.00003
|
1
|
0.0036
|
2
|
0.002
|
5
|
|
|
+
|
0.14
|
71 Lu
|
180
|
0.9
|
|
|
0.4 (*)
|
0.0020
|
|
|
6
|
|
|
0.05
|
0.14
|
72 Hf
|
1200
|
6.0
|
|
|
6 (*)
|
0.030
|
2
|
0.002
|
20
|
|
|
3
|
0.17
|
73 Ta
|
900
|
4.5
|
|
|
10 (*)
|
0.056
|
|
|
640
|
|
|
0.5
|
0.07
|
74 W
|
90
|
3.6
|
|
|
15
|
0.110
|
4
|
0.004
|
20
|
2
|
|
2
|
|
75 Re
|
480
|
2.4
|
6
|
0.03
|
2.4 (*)
|
0.012
|
4
|
0.004
|
20
|
|
|
|
|
76 Os
|
60
|
0.3
|
1.2
|
0.006
|
0.14 (*)
|
0.0007
|
2
|
0.002
|
44
|
|
|
|
|
77 Ir
|
300
|
1.5
|
0.3
|
0.0015
|
11 (*)
|
0.054
|
4
|
0.004
|
14
|
|
|
|
|
Продолжение таблицы 21.
|
Пределы определения элементов (6
)
|
Элемент
|
AAS-Flame
|
AAS-Graphite furnace
|
ICP-AES
|
ICP-MS
|
AES-Arc
|
XRF
|
INAA
|
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock
(ppm)
|
Solution
g/ml
|
Rock [1]
(ppm)
|
Rock [2]
(ppm)
|
Rock [1] (ppm)
|
Rock [3] (ppm)
|
Rock [1] (ppm)
|
78 Pt
|
42
|
0.21
|
0.12
|
0.0006
|
22 (*)
|
0.11
|
2
|
0.002
|
14
|
|
|
|
|
79 Au
|
6.
|
0.03
|
0.006
|
0.00003
|
10
|
0.034
|
1
|
0.001
|
13
|
|
|
0.003
|
|
80 Hg
|
102
|
0.51
|
0.12
|
0.0006
|
10 (*)
|
0.050
|
4
|
0.004
|
100000
|
0.4
|
|
|
|
81 Tl
|
12
|
0.06
|
0.006
|
0.00003
|
16 (*)
|
0.080
|
2
|
0.002
|
6
|
0.06
|
|
|
|
82 Pb
|
1 (*)
|
0.06
|
0.0035
|
0.000021
|
20
|
0.084
|
|
|
40
|
2
|
6
|
|
|
83 Bi
|
5 (*)
|
0.12
|
0.0014
|
0.00003
|
20
|
0.068
|
2
|
0.002
|
2
|
0.06
|
|
|
|
84 Po
|
|
|
|
|
|
|
|
|
|
|
|
|
|
85 At
|
|
|
|
|
|
|
|
|
|
|
|
|
|
88 Ra
|
|
|
|
|
|
|
|
|
|
|
|
|
|
89 Ac
|
|
|
|
|
|
|
|
|
|
|
|
|
|
90 Th
|
|
|
|
|
30
|
0.200
|
4
|
0.004
|
45
|
6
|
9
|
0.4
|
1.0
|
92 U
|
90 (*)
|
90
|
0.09
|
0.09
|
80
|
0.674
|
2
|
0.002
|
430
|
|
6
|
0.3
|
0.5
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Примечание: AAS-Flame - пламенная атомно-абсорбционная спектроскопия;
AAS-Graphite furnace - атомно-абсорбционная спектроскопия с графитовым
атомизатором;
ICP-AES - атомно-эмиссионная спектроскопия
с индуктивно-связанной плазмой;
ICP-MS - масс-спектрометрия с индуктивно-связанной
плазмой;
AES-Arc - атомно-эмиссионная спектроскопия
с дуговой атомизацией, (Cu)- медные электроды, (C)- графитовые электроды;
XRF - рентгенофлуоресцентная спектроскопия;
INAA - инструментальный нейтронно-активационный анализ.
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